Convenient Preparation of Tetraarylphosphonium Halides
نویسندگان
چکیده
منابع مشابه
Convenient preparation of fatty ester cyclic carbonates
The cyclic carbonate moiety finds many industrial applications because of its unique chemistry and properties. Phosgene, a highly toxic and corrosive reagent, has been utilized in the past to prepare low yields of fatty ester compounds (1) that contain a five-membered cyclic carbonate group. Herein, we show (CH3)4N HCO3, tetramethylammonium hydrogen carbonate (TMAHC), to react efficiently with ...
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A P-C bond-forming reaction has been applied to the convenient preparation of tetraarylphosphonium polyelectrolytes (TPELs) from aryl dihalides and diphenylphosphine. A TPEL having a thermal decomposition temperature of 460 °C that is also stable to heating at 65 °C in 6 M NaOH(aq) for at least 24 h has been prepared by this method.
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Organic phosphonium salts have served as important intermediates in synthetic chemistry. But the use of a substituent on the positive phosphorus as a nucleophile to construct C-C bond remains a significant challenge. Here we report an efficient transition-metal-free protocol for the direct nucleophilic arylation of carbonyls and imines with tetraarylphosphonium salts in the presence of caesium ...
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Irradiation of electron-donating substituted phenyl halides (fluorides and chlorides) or esters (mesylates, triflates and phosphates) in aqueous MeCN in the presence of KCN gives the corresponding benzonitriles in 48 to 100% yield through an ArSN1 reaction with the intermediacy of a triplet phenyl cation.
متن کاملA Convenient Preparation of Anhydrous Alkali Metal Thiocarboxylates
Alkali metal salts of thiocarboxylic acid, especially anhydrous salts, are of the most important starting materials. However, only a limited amount of information on their preparation and spectral data has been available because of their strong hygroscopicity [1]. Recently, the convenient preparation methods of a series of anhydrous alkali metal dithiocarboxylates were developed [2]. This resul...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1983
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.56.2869